Novel acid treated biomass: Applications in Cu2+ scavenging, Rhodamine B/Cu2+ binary solution and real textile effluent treatment

INYINBOR, A.A and ADEKOLA, F.A and Dada, Adewumi O. and Oluyori, Abimbola and Olatunji, Gabriel Ademola and Fanawopo, O.F and Oreofe, A.T and Abodunrin, T.O (2018) Novel acid treated biomass: Applications in Cu2+ scavenging, Rhodamine B/Cu2+ binary solution and real textile effluent treatment. Environmental Technology and Innovation, 13. pp. 37-47.

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Abstract

A novel adsorbent prepared from the waste of Irvingia gabonensis nut (ADN) was used for scavenging of Cu2+ from aqueous solution. Various adsorption operational parameters were investigated in order to establish the behavior of ADN before further studies. The efficacy of ADN in concurrent removal of rhodamine B (RhB) dye and Cu2+ in a binary solution of RhB/Cu2+ was also investigated. Finally the potency of ADN in the treatment of real textile effluent was ascertained. Optimum adsorption of Cu2+ occurred at pH of 5.5 and high temperature favored Cu2+ removal. Pseudo second order kinetic best described the uptake of Cu2+ onto ADN. Maximum monolayer adsorption capacity was obtained to be 103.09 mg/g. The Dubinin Radushkevich (D-R) isotherm as well as thermodynamic parameter suggests that adsorption of Cu2+ onto ADN was chemical in nature. Percentage removal of Cu2+ in single solution at optimum time was 94.70 % while synergistic effect of RhB moved this to 99.54 % removal in the binary solution. ADN was highly efficient for the removal of dye and other organic pollutants in the real textile effluent with 100 % removal of some organic pollutant.

Item Type: Article
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Engineering, Science and Mathematics > School of Chemistry
Depositing User: ADEJUMOKE INYINBOR
Date Deposited: 16 Jan 2019 10:29
Last Modified: 11 Sep 2019 12:45
URI: https://eprints.lmu.edu.ng/id/eprint/1780

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