EFFECT OF TEMPERATURE AND PERCENTAGE OF INITIAL CATALYST ON THE IN-SITU PRODUCTION OF BIO-DIESEL FROM CASTOR OIL BEAN SEED USING RESPONSE SURFACE METHODOLOGY

DAIRO, O. U. and Olayanju, T.M.A. and AJISEGIRI, E. S. A. and AWONORIN, S. O. and ALAMU, O. J. (2011) EFFECT OF TEMPERATURE AND PERCENTAGE OF INITIAL CATALYST ON THE IN-SITU PRODUCTION OF BIO-DIESEL FROM CASTOR OIL BEAN SEED USING RESPONSE SURFACE METHODOLOGY. Journal of Natural Sciences, Engineering and Technology, 10 (1). pp. 163-177.

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Abstract

The use of vegetable oil and animal fats for biodiesel production has recently become a great concern because of the competition with food materials. As the demand for vegetable oil increase tremendously in recent years it has become impossible to justify the use of these oils for fuel production. Insitu trans-esterification process uses the oil (triglycerides) in the oil seed directly without the need for initial extraction as compared with the conventional trans-esterification. Castor oil bean seed contains between 35 and 55% oil and does not compete with food grade oil because of the seed’s toxicity. This study evaluated the effect of temperature and percentage of initial catalyst on yield of castor ethyl ester. Raw castor oil bean seed kernel at moisture content of 4.68 % (db) was subjected to in-situ trans-esterification in a batch processor with ethanol as the solvent and sodium hydroxide as the catalyst. Central composite design (CCD) of the Response surface methodology was applied to evaluate the main and interactive effects of initial catalyst amount (0.5 – 1.5%) and reaction temperature (40 – 70OC), on yield of castor ethyl-ester, at reaction time of 120 minutes and alcohol-seed weight ratio of 1:1. A quadratic non-linear polynomial model was obtained to describe the effect of the factors on yield. The model was significant (P< 0.05) with a non- significant Lack-of-Fit value (P< 0.05) and R2 value of 0.944. Second order response surfaces and contour plots obtained from the model revealed that initial catalyst amount was the more effective factors on yield while reaction temperature had less effect. The Temperature–percentage of initial catalyst interaction was small and negative, due to the combined effects of formation of by-products (soaps) and saponification. The biodiesel produced from ground castor oil bean seed during this study met the requirements of ASTM standard D6751-02 but specific gravity was higher than the ASTM standard confirming that biodiesel produced from castor bean seed using the in-situ technique can be used as replacement fuel for fossil diesel.

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